Microstructure and coloring mechanism of iron spots on bluish white porcelain from Jingdezhen of the Song Dynasty

Jingdezhen is famous for its bluish white (Qingbai) porcelains of the Song Dynasty, and those decorated with iron spots are distinctive among them. Herein, iron spots on a bluish white porcelain were investigated using a series of microscopic and spectroscopic characterizations. We found the decreasing iron content from more than 8 wt% to about 2 wt% during the glaze color transition from rusty to brown and finally into green, which built a connection on the coloring mechanism of iron-rich crystallized glaze and celadon glaze. We identified the rare ε-Fe₂O₃, a promising magnetic material, in both the dark brown crystals and the triangular crystals in the rusty area, which is its first discovery among bluish white porcelains. Based on these findings, we discussed the coloring mechanism of iron-spot decoration along with the physical form of the iron oxide crystals, indicating the partially reducing atmosphere during firing process.     

Estimates of daily oxygen consumption,carbon dioxide and methane emissions,and heat production for beef and dairy cattle using spot gas sampling

A simulation study was conducted to examine accuracy of estimating daily O₂ consumption, CO₂ and CH₄ emissions, and heat production (HP) using a spot sampling technique and to determine optimal spot sampling frequency (FQ). Data were obtained from 3 experiments where daily O₂ consumption, emissions of CO₂ and CH₄, and HP were measured using indirect calorimetry (respiration chamber or headbox system). Experiment 1 used 8 beef heifers (ad libitum feeding; gaseous exchanges measured every 30 min over 3 d in respiration chambers); Experiment 2 used 56 lactating Holstein-Friesian cows (restricted feeding; gaseous exchanges measured every 12 min over 3 d in respiration chambers); Experiment 3 used 12 lactating Jersey cows (ad libitum feeding; gaseous exchanges measured every hour for 1 d using headbox style chambers). Within experiment, averages of all measurements (FQALL) and averages of measurements selected at time points with 12, 8, 6, or 4 spot sampling FQ (i.e., sampling every 2, 3, 4, and 6 h in a 24-h cycle, respectively; FQ12, FQ8, FQ6, and FQ4, respectively) were compared. Within study a mixed model was used to compare gaseous exchanges and HP among FQALL, FQ12, FQ8, FQ6, and FQ4, and an interaction of dietary treatment by FQ was examined. A regression model was used to evaluate accuracy of spot sampling within study [i.e., FQALL (observed) vs. FQ12, FQ8, FQ6, or FQ4 (estimated)]. No interaction of diet by FQ was observed for any variables except for CH₄ production in experiment 1. No FQ effect was observed for gaseous exchanges and HP except in experiment 2 where CO₂ production was less (5,411 vs. 5,563 L/d) for FQ4 compared with FQALL, FQ12, and FQ8. A regression analysis between FQALL and each FQ within study showed that slopes and intercepts became farther from 1 and 0, respectively, for almost all variables as FQ decreased. Most variables for FQ12 and FQ8 had root mean square prediction error (RMSPE) less than 10% of the mean and concordance correlation coefficient (CCC) greater than 0.80, and RMSPE increased and CCC decreased as FQ decreased. When a regression analysis was conducted with combined data from the 3 experiments (mixed model with study as a random effect), results agreed with those from the analysis for the individual studies. Prediction errors increased and CCC decreased as FQ decreased. Generally, all the estimates from FQ12, FQ8, FQ6, and FQ4 had RMSPE less than 10% of the means and CCC greater than 0.90 except for FQ6 and FQ4 for O₂ consumption and CH₄ production. In conclusion, the spot sampling simulation with 3 indirect calorimetry experiments indicated that FQ of at least 8 samples (every 3 h in a 24-h cycle) was required to estimate daily O₂ consumption, CO₂ and CH₄ production, and HP and to detect changes in those in response to dietary treatments. This sampling FQ may be considered when using techniques that measure spot gas exchanges such as the GreenFeed and face mask systems.     

波形驱动下多参数约束高分辨率反演方法——以四川盆地渝西地区龙马溪组页岩气为例

基于叠后地震波形指示反演在薄储层预测方面的优势，以及叠前弹性参数较叠后弹性参数信息更丰富、对储层的敏感性更高的特点，根据岩石物理资料，应用地震驱动+储层构型约束的高精度叠前随机反演方法，探寻定量表征优质薄页岩的技术，以期为深层页岩气地质甜点预测提供技术支撑。首先，基于道集波形相似性、AVO特征和空间距离的三变量优选方法提取结构相似的井数据作为空间估值样本，然后建立待判别道集初始模型；其次，以统计的弹性阻抗作为先验信息，应用“基于叠前道集特征指示的马尔科夫链-蒙特卡洛随机模拟算法”进行叠前地震波形指示反演，最终得到高精度的叠前弹性参数反演成果。实际应用表明，应用所提方法有效预测了龙一段一亚段1-2小层优质页岩厚度，基于特征参数的井震高频模拟精确模拟了龙一段一亚段1-2小层地质甜点参数，为页岩气勘探提供了技术支撑。     

Effect of marinating ingredients on temperature-induced denaturation of hemoglobin and its relation to red blood spot formation in cooked chicken breast

Red blood spot (RBS) commonly found in cooked chicken breast has caused severe economic loss as it is perceived as a sign of undercooked product. The objectives of this study were to investigate the cause of RBS as related to common ingredients used in marination, based on both chicken breast and isolated chicken hemoglobin (Hb) models. The effect of sodium chloride (NaCl), sodium tripolyphosphate (STPP), and glucose on thermal denaturation of Hb was investigated along with the extent of RBS formation in cooked marinated chicken breast. After vacuum tumbling for 65 min and subsequent storage at 4 °C for 20 hr, STPP and glucose were not absorbed into the center of chicken breast. However, Na⁺ was absorbed after 12 hr storage. The denaturation temperature (T_d) of isolated chicken Hb decreased to 65.8 °C in the presence of 1.5 M NaCl, while that of the control was 69.4 °C. STPP at pH 9 decreased T_d of Hb to 61.4 °C. The alkaline pH induced by STPP destabilized the Hb structure. RBSs were observed at 100% incidence when cooked to core temperatures of 50 and 70 °C for 1 min. RBSs were completely eliminated at core temperature of 85 °C. The ingredients used during marination appeared to have a minimal effect on RBS formation due to their limited absorption into the chicken breast. The cooking temperature is a major factor governing RBSs, as it directly affects the denaturation of Hb.     

Enhancing nugget size and weldable current range of ultra-high-strength steel using multi-pulse resistance spot welding

ABSTRACT

This paper presents an innovative approach that uses a pulse-profile to improve the welding quality of CP1180 steel in resistance spot welding process. Three pulses with two cooling times were used in the developed multi-pulse welding (MPW) schedule. The experimental results show that the first pulse increases the contact area between the sheets to improve the current flow pattern. The second pulse was designed to extend the sheet-to-sheet contact area and corona bond for preventing rapid nugget growth. Using these designs, the nugget size was maximised through the third pulse. The maximum nugget size using the designed MPW schedule was 18.5% greater than that of the single-pulse welding schedule and the weldable current range was extended by 130%.     

Hydrogen storage property of as-milled La7RE3Mg80Ni10 (RE = Sm,Ce) alloys

Element replacement and mechanical milling are considered as the most effective ways to improve Mg-based alloys in their hydrogen storage performance. The as-milled La₇RE₃Mg₈₀Ni₁₀ (RE = Sm, Ce) alloys were prepared in this experiment by introducing both element replacement (replacing La by Ce or Sm partially) and mechanical milling technologies. The influence made by different replacing elements on the structure and hydrogen storage property of La₇RE₃Mg₈₀Ni₁₀ (RE = Sm, Ce) alloys was investigated in detail. X-ray diffraction, transmission electron microscope, automatic Sievert apparatus, thermogravimetry and differential scanning calorimetry were used to investigate the experimental alloys. The experiment reveals that a nanocrystalline and amorphous structure appears after mechanical milling. Moreover, comparing with the RE = Sm alloy, the RE = Ce alloy has a superior hydrogen desorption property, including larger hydrogen absorption capacity, faster hydriding/dehydriding rate, lower onset hydrogen desorption temperature, and lower dehydrogenation activation energy.     

Evaluation of expanded gamut software solutions for spot color reproduction

Expanded gamut printing is an approach in color reproduction that expands the color gamut of conventional CMYK printing processes via the use of additional colorants, such as Orange, Green, and Violet inks. This study evaluates the ability of commercial color management software to create an accurate solution for an expanded gamut printing system. In this study, two printing processes were used, an Epson SureColor P9000 inkjet printer/proofer and an HP Indigo 7900 digital production press, both with 7-color expanded gamut ink sets. Software solutions from Alwan, CGS ORIS, ColorLogic, GMG Color, Heidelberg, and Kodak were evaluated. The systems were tested to see how well they could reproduce the colors in the entire PANTONE+ Solid Coated spot color library. It is shown that the solutions are able to reproduce 89% to 94% of the spot colors on the Epson P9000 inkjet printer and 77% to 87% of the library on the Indigo 7900, both to less than two CIEDE2000 (a typical tolerance in label and packaging work). The number of color patches in expanded gamut characterization test charts was noted, as this is still an area of proprietary, nonstandardized working practice. There are many different colorant combinations that can make the same color in expanded gamut printing. The ink build created by the different software solutions was studied, as it relates to press stability through appropriate choice of colorants. Pantone and Adobe provide everyday commercial tools for expanded color workflows. The study identified some issues with products from these companies that could confuse a less-skilled user in a busy production environment. The conclusion of the study is that expanded gamut solutions for spot color printing produce totally acceptable results for digital printing processes; expanded gamut printing is ready, here and now. The findings show that expanded gamut printing can replace cumbersome conventional spot color workflows creating considerable savings and advantages, especially for label and packaging printers.     

转速对2524铝合金搅拌摩擦点焊组织与性能的影响

对2524铝合金薄板进行搭接搅拌摩擦点焊试验, 研究了搅拌头转速对其组织与性能的影响。结果表明, 随转速增加, 焊点外侧飞边越加严重, 组织畸变程度增加, 焊核区宽度增大, 有效连接宽度先增大后减小。母材区硬度最大, 热影响区硬度最低;在焊核区内, 显微硬度随转速增加而增大, 当转速为1 100 r/min时达到最大133.9HV, 而热影响区在300 r/min时硬度最大。在单向拉伸试验中, 接头剪切强度随转速增加先增大后减小, 在700 r/min时达到最大值3 510 N;接头呈现出两种断裂模式: 即低转速下平行于两板面断裂和高转速下沿倾斜方向断裂;断口呈现明显的剪切韧窝形态, 韧窝小而浅, 焊接接头为韧性断裂。     

Effect of metallurgical evolution during post-weld aging treatment on localised corrosion of resistance spot welding joints of A286 superalloy

The combined effect of resistance spot welding and precipitation hardening on the localised corrosion of A286 superalloy is studied. The specimens tested by double loop electrochemical potentiokinetic reactivation were welded in the solution treated condition, and then subjected to different precipitation hardening treatments. For both base metal and weld nugget, the maximum localised corrosion is reached when η phase is clearly observable. The fact that the localised corrosion resistance of weld nugget is different from that shown by base metal may be explained by the segregation of Ni and Ti towards the interdendritic region of weld nugget (studied by using scanning electron microscope/energy dispersive X-ray analysis).     

Embedding Ag or Au nanoparticles within the nano-sized wall of YbPO4:Er3+ inverse opals and resulting enhanced upconversion luminescence

Metal nanoparticles preparation in the interior of nanoscale skeleton of inverse opals made up of crystallized matrix is more difficult than the preparation of pure inverse opals. In the present work, the Ag or Au nanoparticles embedded YbPO₄:Er³⁺ inverse opals were prepared by a simple approach, which involved the infiltration of opal template by using the transparent YbPO₄:Er³⁺ sol including silver nitrate or chloroauric acid and the sintering at high temperature. The 20–30?nm Au or 5–10?nm Ag nanoparticles were formed in the interior of nanoscale skeleton in the YbPO₄:Er³⁺ inverse opals, and the Ag or Au nanoparticles embedded YbPO₄:Er³⁺ inverse opals were prepared. The influence of Ag or Au nanoparticles on the upconversion photoluminescence of YbPO₄:Er³⁺ inverse opal was studied, and the upconversion luminescence enhancement induced by the Ag or Au nanoparticles was observed. The mechanisms of upconversion luminescence enhancement of YbPO₄:Er³⁺ inverse opals induced by Ag or Au nanoparticles were discussed. The enhancement of upconversion luminescence induced by Ag nanoparticles was attributed to the enhancement of the excitation field, and the enhancement of upconversion emission induced by Au nanoparticles was related to the increasing of the radiation decay rate of Er³⁺.